Reactions of Hexabutylditin with ligands such as β-diketones and β-Ketoesters
Author & Affiliation:
Deepika Bansal
Department of Chemistry, University of Rajasthan, Jaipur-302004 (INDIA)
Man Mohan
Department of Chemistry, University of Rajasthan, Jaipur-302004 (INDIA)
R.K. Mittal
Department of Chemistry, University of Rajasthan, Jaipur-302004 (INDIA)
Keyword:
Hexabutylditin, ligands, b-diketones and b-Ketoesters
Issue Date:
December 2008
Abstract:
The reactions of hexabutylditin with b- diketones and b- ketoesters in the molar ratio of 1:2 were studied in the medium of anhydrous benzene. Complexes of the type R3Sn-L (where R= C4H9) have been synthesized. All the reactions were not so facile and tin-tin bond was cleaved in preference to the tin -carbon bond. The resulting tin (IV) complexes of b-diketones and b-ketoesters were isolated in the form of brown yellow solids or semi-solids. They are soluble in common organic solvents. These complexes are supposed to have trigonal bipyramidal geometry.
Pages:
519-522
ISSN:
2319-8052 (Online) - 2231-3478 (Print)
Source:
PDF:
DOI:
jusps-B
Share This:
Copy the following to cite this article:
D. Bansal; M. Mohan; R. Mittal, "Reactions of Hexabutylditin with ligands such as β-diketones and β-Ketoesters ", Journal of Ultra Scientist of Physical Sciences, Volume 20, Issue 3, Page Number 519-522, 2018Copy the following to cite this URL:
D. Bansal; M. Mohan; R. Mittal, "Reactions of Hexabutylditin with ligands such as β-diketones and β-Ketoesters ", Journal of Ultra Scientist of Physical Sciences, Volume 20, Issue 3, Page Number 519-522, 2018Available from: http://ultraphysicalsciences.org/paper/1333/
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License
