The electrical conductivity (s) and Seebeck Coefficient (S) studies have been reported from 500 K to the melting point (1150 K) the solidified melt of the superionic system Li₂O : V₂O₅ : WO₃. The material is not hygroscopic and does not have a real superionic phase, however, in the temperature range 320 K to 550 K it has high ionic conductivity (s_i = 2.1 × 10^-2 W^-1m^-1 at 330K) with small (0.21 eV) activation energy but relatively large (between 10 to 15 percent) electronic conductivity. Anomaly observed in s and S data is also reflected in molar magnetic susceptibility (c_M) and dielectric constant (K) results.