Ligation of s - aryl complexes of Iridium by Heterocyclic thioamide
Author:
R.N. Pandey* and Sheo Shankar Kumar
Affiliation:
P>G. Centre of Chemistry(M.U) College of Commerece Patna India
Email:-rameshwarnath_pandey@yahoo.com
Keyword:
Oxidative addition, phenyl ion, Heterocyclic thioamides
Issue Date:
August 2011
Abstract:
Oxidative addition of phenyl ion to Vaska's compound, [IrCl(CO)(Pf3)2] in presence of phenyl, parachlorophenyl, paramethoxyphenyl, paraethoxyphenyl and paratolyl derivatives of 1-substituted tetrazoline-5-thione are carried out and structure and mode of metal ligand bonding are investigated using spectral (IR, UV-Vis & `HNMR) and other physico-chemical data. The two Pf3 molecules are at trans in octahedral [IrCl(CO)(Pf3)2(ligand)]BF 4isolated products.
Pages:
459-464
ISSN:
2319-8052 (Online) - 2231-3478 (Print)
Source:
PDF:
DOI:
jusps-B
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R.N. Pandey* and Sheo Shankar Kumar , "Ligation of s - aryl complexes of Iridium by Heterocyclic thioamide ", Journal of Ultra Scientist of Physical Sciences, Volume 23, Issue 2, Page Number 459-464, 2016Copy the following to cite this URL:
R.N. Pandey* and Sheo Shankar Kumar , "Ligation of s - aryl complexes of Iridium by Heterocyclic thioamide ", Journal of Ultra Scientist of Physical Sciences, Volume 23, Issue 2, Page Number 459-464, 2016Available from: http://ultraphysicalsciences.org/paper/636/
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